Rovers then return to the Keepmoat for a home double header over four days as they host Port Vale and Preston North End.
The first derby of the season sees Paul Dickov’s men travel to Barnsley on September 6 before hosting Chesterfield on September 20.
Rovers visit Glanford Park on October 4 and host title favourites Sheffield United on November 15.
Boxing Day sees Rovers host Coventry and they end 2014 with a trip to Peterborough.
Paul Dickov’s side welcome Barnsley to the Keepmoat on January 17 before their first visit to Chesterfield’s Proact Stadium on January 31.
Sheffield United are the hosts on Easter Monday, April 6, while Rovers close their campaign with a home fixture against near-neighbours Scunthorpe.